Study on Growth Habit, SHG and Thermal Properties of Urea Phosphate Doped KDP Crystals

Pure and doped with Urea Phosphate single crystals of Potassium Dihydrogen Phosphate (KDP) were grown by the low temperature solution growth method, adopting the technique of slow evaporation of the solvent for nonlinear optical applications. The change in the growth habit of the doped KDP crystals has been reported. The study confirms the decrease in the growth rate along c-axis with increasing the dopant concentration. The doping of the Urea Phosphate in the grown crystal has been confirmed qualitatively by the FT-IR spectroscopy. Form the UV-Visible-NIR transmission study; it was observed that the transparency of the crystal increases with dopant concentration. Thermo Grav imetric Analysis shows that the thermal stability of the crystal decreases with dopant concentration. The crystal structure of doped crystal was determined from Powder X-Ray diffract ion studies. The improvement in Second Harmonic Generation efficiency of doped crystal has also been reported.


Introduction
Potassium Dihydrogen Phosphate (KDP) crystal is most widely used and thoroughly studied nonlinear optical (NLO) crystal. The attempts have been made to modify the properties favorable for NLO applications and growth rate o f the KDP crystal by either changing the growth conditions or by adding different impurit ies [1][2][3][4][5][6]. The Ethylenediamine tetra acetic acid (EDTA) inhibits growth of KDP and acts as scattering centers in grown crystals [7] wh ile on the other side it prevents number of nucleation's, increasing metastable zone width, which helps in growing big size good quality crystal [8]. Azo -organic dye A maranth gets absorbed and colors the pyramidal section (1 0 1) o f the crystals and Sunset yellow FCF mod ifies the crystal habit and color of KDP. It decreases size of prismat ic section of the crystal [9]. The increase in mean growth rate along the[001] direction has been reported with an increase in the concentration of trivalent impurity Cr(III) in the KDP solution wh ile the growth rate along[100] direction is not altered [10]. A similar effect of Fe(III) and Cr(III) on the growth rate of KDP crystals has been reported by Owczarek and Sangwal [11]. Amino acids have very large optical nonlinearity, assigned to the chiral structure, used by many workers to imp rove the NLO, optical, thermal and mechanical properties of KDP using as a dopant [12,13].
Urea has been reported as a NLO material. Although it's optical and mechanical properties are comparable to those of KDP, but its crystallization and handling is rather difficult as it is highly hygroscopic. Different derivatives of urea have been studied for NLO applications. So me of them found useful for NLO applications [6,[14][15][16][17][18]. The Urea and Urea derivates Thiourea, N'N dimethyl Urea have been tried as a dopent in KDP [19][20][21][22].
As KDP is being widely used in NLO applications and demands to modify its properties, the research work on the modifications of the optical, thermal, mechanical and NLO properties and the growth rate of the KDP crystal by using different dopants is still going on [23][24][25]. The urea and urea derivatives have high NLO efficiency and can be used as dopant to modify the properties of KDP crystal. In the present work, an attempt has been made to catch the properties of Urea derivative; Urea Phosphate and add it with KDP to investigate the effects. The growth of Urea Phosphate doped KDP crystals and their characterizat ions have been presented. Improvement in the SHG efficiency has been reported. Modification in the growth habit has also been observed.

Bulk Crystal Growth
The solubility's of the pure (KDP) and 2mo l%, 4mo l% and 6mol% Urea Phosphate doped KDP (KU1, KU2 and KU3 respectively) crystals were measured gravimetrically in double distilled water in the temperature range 30-60℃ ( Figure 1). The materials have positive solubility gradient with temperature in water. The double distilled water was used as a solvent throughout the experiment.
Good quality crystals of pure and doped KDP were grown within 3-4 weeks. In doped crystals, growth rate along c-axis is found to be decreased. The pH of the solutions was ranged fro m 4.5 to 4.7. The photographs of some of the grown crystals are shown in Figure 2.

Characterization
The FT-IR study was carried on the pure and doped KDP crystals to confirm qualitatively, the doping of the dopants in the crystals. Transparency of the crystals in the wavelength range 190-1100n m was studied by using UV-1700 SHI-MADZU Spectrophotometer. Powder XRD patterns were recorded on XPERT Pro Diffractometer and analyzed by Powder X software. The results have been presented. SHG efficiency was measured by employing Kurt z and Perry method. The SEM images of the crystals on the pyramidal section (1 0 1) were taken.

Growth Habi t
The morphology of KDP crystals has tetragonal pris matic (100) and (010) faces and two tetragonal pyramids with the faces (101) and (011). The chemical bonds formed in KDP crystal between the growth units are the ones between K + cations and H 2 PO 4 anions, as well as the hydrogen bonds of the adjacent H 2 PO 4 groups. The prismatic faces of KDP grow by stacking positive K + and negative H 2 PO 4 ions alternately leaving the face {100} charged neutrally and adsorbs the metal cations and organic molecules, which can form hydrogen bonds. The pyramidal growth sectors {101} are stacked in the mode of two layers of cations and two layers of anions alternately. Each layer consists completely of either cations or anions. The potassium ions join into the lattice site rapid ly as the negatively charged double layer (H 2 PO 4 -) is formed, because of its small volu me, light weight and no preferred orientation required as co mpared with H 2 PO 4 -. Thus, the pyramidal face is always positively charged throughout the growth process. The anions get adsorbed on the positively charged (101) planes and continues growth of the crystal in the direction [26]. It has evidences that the metallic cations and dyes influence the growth of prismat ic (100) section and pyramidal (101) section of KDP crystals [27][28][29][30][31].
In the present study, the growth rate of doped crystals along c-axis is found to be decreased. In the Urea Phosphate doped KDP crystals, the decrease in the growth rate along c-axis, is possibly because of accommodations of the bigger size an ion CO(NH 2

Fourier Transform Infrared (FT-IR) Study
The FT-IR spectra of pure and doped KDP crystals (Figure 4) were recorded on Perkin Elmer FT-IR Spectrophotometer within the wavenumber range 600 to 4000 cm -1 .
In the FTIR spectrum of pure KDP crystal, the observed absorption peak at 3734.1cm -1 corresponds to the P-OH stretching, 2365.12 cm -1 to O-H and P-OH stretching, 1750.24 cm -1 to the P-O-H bending, 1279.19 cm -1 to O-H deformation and P=O stretching and 915.2 cm -1 attributed to P-OH stretching and HO-P-OH bending.
In the FT-IR spectra of Urea Phosphate doped KDP crystals, same peaks with slight change in positions due to hydrogen bonding have been observed with some addit ional peaks. These additional peaks observed in the range 3000 cm -1 -2800 cm -1 corresponds to the C-H stretching. The peaks

UV-Visible-NIR Spectroscopy
The transmission study on the grown crystal is important. The crystal should be transparent to the fundamental and second harmonic wavelength in order to have use in Second Harmonic Generation (SHG) applications. The transmission of the crystals over wavelength range 190n m-1100n m was measured on UV-1700 Sh imad zu Spectrophotometer. 3mm thick crystal wafers were cut, polished and used for the transmission study. The increase in the transparency of the doped crystals has been observed. The increase in the doping level improves the fine cutoff at lower wavelength side but no change in the cutoff wavelength has been observed. UV-Vis-NIR spectrums of pure and doped KDP crystals are shown in Figure 5.

XRD Study
The powder XRD patterns (Figure 6) of the pure, 6mol% UPP doped KDP crystals were recorded using X-ray Diffractometer XPERT-PRO with Cu Kα rad iations (1.54060Ǻ, 40 mA , 45 kV). The powder samples were scanned in steps of 0.0170° for a time interval of 10.3359 sec over a 2θ range of 10.0144-119.9874°. The unit cell parameters have been calculated (Table 1) using software Powder X.

SHG Efficiency Measurement
Kurtz and Perry method [32] was emp loyed to measure the SHG efficiency of the grown crystals in reference with the pure KDP. In the measurement, Q-switched, mode locked Nd:YA G laser of wavelength 1064n m of peak power 2.35mJ, pulse duration 8 ns and repetition rate 10Hz was used. The output was measured at wavelength 532n m. The SHG efficiencies of the doped crystals found to be mo re with reference to pure KDP (Tab le 2).

Ther mal Study
The Thermo Gravimetric Analysis (TGA) of KU3 was carried out by recording TGA curve on Perkin Elmer TGDTA at a heating rate of 15℃/ min under Argon atmosphere. Pure KDP crystal is found to be stable up to temperature 235℃ [13]. The TGA curve of KU3 (Figure 7) re-veals the maximu m weight loss is in the temperature range 195-355℃. Prolonged heating does not produce any loss. The weight loss starts earlier and ends latter as co mpared to the KDP. This weight loss corresponds to the decomposition of the KDP and Urea Phosphate.

Conclusions
The pure and doped KDP crystals with different concentration of Urea Phosphate of best quality were grown fro m solution within 3-4 weeks.
The doping in the crystals was qualitatively confirmed by the FTIR spectroscopy.
The SHG efficiency study shows the imp rovement in the efficiency of the doped crystals.
Increasing transparency with concentration of dopant in the host crystal has been confirmed by the UV-Vis -NIR Spectroscopy.
The lattice parameters have been determined fro m powder XRD study. Doping in the KDP crystals leads to negligib le change in the lattice parameters, and the crystal system and space group of the KDP retained.
External mo rphology of the crystal reveals the decrease in the growth rate along[001] d irection in all doped KDP crystals. The growth rate decreases with increasing doping level. This decrease in the growth rate is attributed to the attachment of the bigger size an ions on pyramidal faces.
The KU3 crystal is thermally stable up to 195℃.