Aging of Paper Insulation in Natural Ester & Mineral Oil

This paper presents an assessment on aging model of IEEE and IEC standards using thermal model of oil-immersed power transformer for natural ester and mineral oil. For this purpose, a model created for the behaviour of transient thermal performance with aging of natural ester and mineral oils. Thermal model of the transformer is based on thermal-electrical analogy that is calculated separately for natural and mineral oils covering top-oil and hot-spot temperatures. The hot-spot temperature values of each ester/oil are used to calculate aging parameters which include the aging acceleration factor, time dependent relative aging rate and insulation life loss variations. In this study, mineral oil and natural ester are kept under temperatures which are 100°C and 140°C in different periods. Natural ester’s characteristics are higher than mineral oil’s, except its breakdown voltage. In addition, natural ester absorbs more water than mineral oil so it is understood that deformation of the insulating paper in natural ester is lower. Natural ester has important benefits to decelerate aging of insulation. There is a model which is proposed for natural ester oil–immersed transformers and there should be used an aging factor as R to predict remaining life.


Introduction
Today, clean energy is emerging as a new trend in electric power systems. Therefore, green oils have been preferred as liquid insulator in power transformers especially since 2000. Green oils have three most important features, have slow down the impact of the aging process; provide a safe work performance and are biodegradable as close to 100%. Green oils named as the natural esters can be mixed with mineral oils and their utilization rates are increasing every day due to non-toxic and eco-friendly features.
Thermal aging of insulation materials in mineral oil-immersed transformers have been formulated in ANSI/IEEE-C57.91 and IEC-354.91 standards [1,2]. However, these formulas should be revised again for natural ester due to slow down the aging process. There are some differences between IEEE and IEC standards on thermal aging methods for mineral oil-immersed transformers. According to IEEE, normal lifetime of the power transformers equals to 20.55 years, whereas a total life has not been defined by the IEC standards, but it is usually equal to 30 years depending on the aging rate determined by the hot spot temperature [3,4]. Hot spot temperature of natural ester-immersed transformers is higher than that of mineral oil-immersed transformers.
And it is emphasized that the deviation of the hottest temperature between the two is increased with load [5,6] because when the natural ester is compared to mineral oil, viscosity is higher and thermal conductivity is lower [5,6] nevertheless, there is amount of soluble water transferred from Kraft paper to the natural ester more than mineral oils. That's the reason why the paper is slow down aging and less deterioration in natural ester. Other positive features of Natural ester are presented in Table 1.  [7,8]. Natural ester has higher absolute humidity and acidity during the long ageing period [9]. Transformer paper in vegetable oil had larger activation energy. Due to the larger interaction force between water and natural ester molecules, water molecule was easily bonded with natural ester, weakening the hydrolysis process of cellulose. Cellulose is chemically modified by natural ester during thermal aging process [10]. Vegetable oil is an alternative to mineral oil and over the temperature range of 70 o C to 190 o C shows that the use of vegetable oil as a very promising option [11]. Transformer paper is decomposed by water, oxygen, oil acid, high temperatures and eventually degrades to the point where it is no longer an effective insulator [12,13,14]. Aging of Kraft paper in mineral or natural ester oils produced important amounts of CO and CO 2 [12].
This study suggests that determining the difference of aging period between natural ester and mineral oil should be used factor R so it is possible to predict the lifetime of natural ester oil-immersed power transformers easily and nearly correct.

Top-Oil and Hot-Spot Thermal Models
The top oil thermal model is based on the equivalent thermal circuit theory proposed by G. Swift. The differential equation for the equivalent circuit is [15]; where, I pu is the load current per unit. θ A is the ambient temperature, ℃. θo is the top oil temperature, ℃. β is the ratio of load to no-load losses oil τ is the top oil time constant, min.
∆θ oil-R is the rated top oil rise over ambient, K. n is the exponent defines non-linearity. As the same mentioned method, the differential equation used to calculate the hot spot temperature is; θ H is the hot spot temperature, ℃. P EC -R(pu) are the rated eddy current losses at the hot spot location ∆θ H-R is the rated hot spot rise over top oil, K.
H τ is the winding time constant at the hot spot location, min.

Insulation Life Loss
The IEEE guide recommends that users select their own lifetime estimation. In this guide, 180 000 hours (20.55 years) are used as a normal lifetime [3].
It is assumed that insulation deterioration can be modelled as a per unit quantity for a reference temperature of 110℃, the equation for accelerated aging is [3,4]; The IEC guide is applicable mainly for the non-thermally upgraded paper, and the hot-spot temperature is limited to 98℃ at 20℃ ambient temperature. It can be expressed in the following manner [3,4]: (4) The loss of life during a small interval dt can be defined as; (5) The loss of life over the given load cycle can be calculated by; (6) and the per unit loss of life factor is; The insulation loss of life is usually taken to be a good indicator of transformer loss of life.

The Proposed Method and Transient Modelling
In this study, two different models are created in Matlab-Simulink for natural ester and mineral oil immersed power transformers which have the same technical specifications (ONAF-250MVA). Parameters of the power transformer were taken in IEEE Loading Guide and specifications are shown in Table 2.
The established model has two stages. In first stage, ambient temperature and load factor are taken as input parameters. The hot-spot temperatures that will be used in loss of life calculation are found out by using these parameters by running the thermal model. However, the hot spot temperature calculation procedures are different for natural ester and mineral oil immersed transformers.  [6]. For this reason, a lookup table changing as exponential is intended in the model for natural oil immersed transformer according to the studies in literature.
The second phase of the modelling is the calculation of aging characteristics. Here, different equations are recommended for natural ester (revised) and mineral oil (not revised) to calculate the aging acceleration factor as shown in Table 3. In the literature, it is commonly mentioned that vegetable-based oils prolong life of solid insulation between 5 to 8 times at the same temperature. For this purpose a factor (R) should be added to the calculation process of the aging model for natural ester [17].

Experimental Studies
Samples of mineral oil and natural ester are kept under temperatures of 100℃ and 140℃ for different periods. Test results are given by Table 4, and Table 5 respectively. Images of the held samples are also shown in Figure 2. The results show that characteristics of natural ester are higher than mineral oil, except its breakdown voltage. Additionally, as it can be seen that water content results; natural ester absorbs more water than mineral oil. This means that deformation of the insulating paper in natural ester is lower.
In addition, the results of the gas analysis show that CO 2 /CO ratio which defines aging stage of cellulosic insulation material is very different. The ratio is under three for mineral oil, while it is above seven for natural ester.
Equivalent test transformers are operated such condition that corresponds to double rated current in order to evaluate the heating performance of mineral oil and natural ester. Hot spot temperatures are measured by fibre optic sensor. It is observed that the temperature differences of mineral oil and natural ester are between 10℃ and 15℃. The aging characteristic of insulting material is affected from the temperature. The natural ester immersed transformer is more heated than the mineral oil immersed transformer under the same conditions.  According to the some studies on accelerated aging tests in literature, lifetime of the paper aged in natural ester is 5-8 times longer than paper aged in mineral oil at the same temperature values [18]. Actually, the hot spot temperatures taken into account for the aging calculations will be different from each other for natural ester-immersed transformers and mineral oil-immersed transformer. Consequently, as given in section three, the formulas should be revised relatively.

Transient Thermal Characteristics
The load step variation for 750 minutes time duration is shown in Figure 3. Calculation of the hot spot temperature and top-oil temperature for mineral oil-immersed power transformer using thermal model are shown in Figure 4. It can be seen that the temperature rise for the certain time periods does not reach to the steady state point.  Under the same time duration, the hot-spot temperature rise calculated for the natural ester and the mineral oil is shown in Figure 5. The difference of the temperature between the natural ester and mineral oil increases as power factor increases. This is because the thermal resistance and thermal capacity of the natural ester are greater than that of the mineral oil.

Transient Aging Characteristics
In order to determine aging characteristics clearly, the load time duration is increased to 48 hours, and load sample repeats three times in this duration. The following situations are analysed using the model.
· Aging acceleration factor variation · Time dependent relative aging rate variation · Life loss variation Figure 6 (a) and (b) shows the acceleration of aging for natural ester and mineral oil. Although the aging characteristics are the same, the aging acceleration factor of mineral oil is approximately two times higher than that of natural ester. Also, this affects to the relative aging rate. As shown in Figure 7, trend of the relative aging rate instabilities for natural ester and mineral oil decreases as the time increases. The life loss variation of the solid insulation which is misknown as transformer life loss is shown in Figure 8.

Conclusions
The results of this study show that the natural ester has significant benefits in slowing down aging of insulation. Solid insulation life loss variations which is mentioned as 5-8 times slower at the same temperature, experimented by modelling two different 250 MVA power transformers which have the same technical characteristic features for mineral oil and natural ester. The factor R should be added to the proposed model for natural ester and, its temperature rise more than that of mineral oil is also considered in this study. Particularly, natural ester-immersed transformer is very advantageous in the nominal operating conditions. This advantage decreases with increasing load values over the nominal operating condition.